Spot Play Strong
How can you work out which intemrolecular force is strongest in play in a compound?
I know i would firstly look to see if there was a hydrogen bonded to nitrogen, oxygen or fluoride to see if it were a hydrogen bond, e.g. H2O. But i’m stuck as to how to spot the other two, dipole-dipole and van der Waals. Any help? I know the basic principles of them, finding the topic a bit difficult though to be honest
Dipole-dipole is where the molecule is polar. You could look for specific polar bonds such as a C-Br bond which is caused by a large difference in electronegativity. The bromine atom is more electronegative (it draws the electrons towards itself).
Van der waals occur between all molucules, but the closer together they fit and the longer they are the stronger the Van der waals forces are. These are caused by random electron movement creating temporary dipoles which is why they can occur on all molecules. The bigger a molecule is, the more electrons it has, hence the stronger the van der waals forces are.
Remember that hydrogen bonding is stronger than permenant dipole-dipole bonding whereas dipole-dipole is stronger than van der waals.
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